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Arylation of Allylic Alcohols in Ionic Liquids Catalysed by a Pd‐Benzothiazole Carbene Complex
Author(s) -
Caló Vincenzo,
Nacci Angelo,
Monopoli Antonio,
Spinelli Michele
Publication year - 2003
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200390194
Subject(s) - benzothiazole , chemistry , allylic rearrangement , carbene , bromide , ionic liquid , organic chemistry , aryl , medicinal chemistry , solvent , ionic bonding , catalysis , alkyl , ion
The reaction of aryl bromides with allylic alcohols catalysed by a Pd‐benzothiazole carbene complex, in tetrabutylammonium bromide as solvent, leads principally to β‐arylated carbonyl compounds. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)