Synthesis of all Four Stereoisomers of Leucomalure, Components of the Female Sex Pheromone of the Satin Moth,  Leucoma salicis | Zendy

Muto Shinetsu | Zendy; Mori Kenji | Zendy

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Synthesis of all Four Stereoisomers of Leucomalure, Components of the Female Sex Pheromone of the Satin Moth, Leucoma salicis

Author(s) -

Muto Shinetsu,

Mori Kenji

Publication year - 2003

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200390186

Subject(s) - chemistry , pheromone , sex pheromone , stereochemistry , acetylation , botany , biology , biochemistry , gene

Lipase PS‐C(Amano)‐catalyzed asymmetric acetylation of (±)‐4‐( tert ‐butyldiphenylsilyloxy)‐ cis ‐2,3‐epoxy‐1‐butanol afforded the (2 R ,3 S )‐epoxy alcohol and the (2 S ,3 R )‐epoxyacetate, which were converted into all of the four stereoisomers of leucomalure [(3 Z )‐ cis ‐6,7‐ cis ‐9,10‐diepoxy‐3‐henicosene], the female sex pheromone of the Satin moth, Leucoma salicis . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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