An Unprecedented [2+3] Cycloadditive Dimerization of a Transient Thiocarbonyl  S ‐Ylide | Zendy

ElSayed Ibrahim | Zendy; Grønbæk Hazell Rita | Zendy; Øgaard Madsen Jørgen | Zendy; Norrby PerOla | Zendy; Senning Alexander | Zendy

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An Unprecedented [2+3] Cycloadditive Dimerization of a Transient Thiocarbonyl S ‐Ylide

Author(s) -

ElSayed Ibrahim,

Grønbæk Hazell Rita,

Øgaard Madsen Jørgen,

Norrby PerOla,

Senning Alexander

Publication year - 2003

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200390123

Subject(s) - trimethylsilyl , ylide , chemistry , diazo , transient (computer programming) , medicinal chemistry , methane , organic chemistry , computer science , operating system

4‐Chlorophenyl C ‐(phenylsulfonyl)dithioformate reacts with diazo(trimethylsilyl)methane to form 2‐(4‐chlorophenylthio)‐2‐phenylsulfonyl‐4,5‐bis(trimethylsilyl)‐1,3‐dithiolan‐1‐ium (4‐chlorophenylthio)(phenylsulfonyl)methylide. It is assumed that this product is formed by [2+3] cycloadditive dimerization of the transient (trimethylsilyl)methanethial S ‐[(4‐chlorophenylthio)(phenylsulfonyl)methylide]. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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