Organolead‐Mediated Arylations: 2‐(3,3‐Diphenylallyloxy)phenyllead Triacetate as an Internal Free‐Radical‐Trap‐Containing Reagent | Zendy

Fedorov Alexey Yu.  | Zendy; Finet JeanPierre | Zendy

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Organolead‐Mediated Arylations: 2‐(3,3‐Diphenylallyloxy)phenyllead Triacetate as an Internal Free‐Radical‐Trap‐Containing Reagent

Author(s) -

Fedorov Alexey Yu. ,

Finet JeanPierre

Publication year - 2004

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200300784

Subject(s) - chemistry , reagent , benzofuran , trap (plumbing) , radical , copper , medicinal chemistry , organic chemistry , combinatorial chemistry , environmental engineering , engineering

2‐(3,3‐Diphenylprop‐2‐enyloxy)phenyllead triacetate, an arylating reagent containing an internal free radical trap, was synthesised and its behaviour studied in base‐catalysed C ‐arylation reactions and in copper‐catalysed N ‐arylation reactions. The absence of benzofuran derivatives among the products of C ‐ and N ‐arylation reactions excludes the involvement of radical species in these two processes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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