Premium
Organolead‐Mediated Arylations: 2‐(3,3‐Diphenylallyloxy)phenyllead Triacetate as an Internal Free‐Radical‐Trap‐Containing Reagent
Author(s) -
Fedorov Alexey Yu. ,
Finet JeanPierre
Publication year - 2004
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200300784
Subject(s) - chemistry , reagent , benzofuran , trap (plumbing) , radical , copper , medicinal chemistry , organic chemistry , combinatorial chemistry , environmental engineering , engineering
2‐(3,3‐Diphenylprop‐2‐enyloxy)phenyllead triacetate, an arylating reagent containing an internal free radical trap, was synthesised and its behaviour studied in base‐catalysed C ‐arylation reactions and in copper‐catalysed N ‐arylation reactions. The absence of benzofuran derivatives among the products of C ‐ and N ‐arylation reactions excludes the involvement of radical species in these two processes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)