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Novel and Rapid Synthetic Routes to A 3 B‐ and AB 3 ‐Type 21‐Thiaporphyrins and Their Use in the Construction of Unsymmetrical Covalent and Non‐Covalent Porphyrin Arrays
Author(s) -
Gupta Iti,
Agarwal Neeraj,
Ravikanth Mangalampalli
Publication year - 2004
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200300764
Subject(s) - covalent bond , chemistry , porphyrin , combinatorial chemistry , group (periodic table) , stereochemistry , organic chemistry
Novel and very simple methods were developed for the synthesis of 21‐thiaporphyrins having both one functional group (A 3 B) and three functional groups (AB 3 ). These A 3 B‐ and AB 3 ‐type 21‐thiaporphyrin building blocks were used to synthesize both covalently and non‐covalently linked unsymmetrical porphyrin arrays containing N 3 S and N 4 porphyrin cores. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)