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Carrier‐Mediated Transport of Toxic Heavy Metal Ions in Bulk Liquid Membranes
Author(s) -
Brinchi Lucia,
Germani Raimondo,
Mancini Maria Vincenza,
Savelli Gianfranco,
Spreti Nicoletta
Publication year - 2004
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200300622
Subject(s) - chemistry , copper , cadmium , membrane , mercury (programming language) , facilitated diffusion , metal ions in aqueous solution , metal , dichloromethane , inorganic chemistry , ion transporter , ion , environmental chemistry , organic chemistry , solvent , biochemistry , computer science , programming language
Transport through a dichloromethane liquid membrane has been studied to investigate the ability of 1,1,7,7‐tetraethyl‐4‐tetradecyldiethylenetriamine (TE14DT), previously tested for the transport of copper, to act as a carrier for toxic heavy metal ions such as Cd 2+ , Pb 2+ and Hg 2+ . The carrier displayed a remarkable capability to extract all the metal ions from the source to the organic phases but only cadmium was efficiently transported across the membrane. The experimental conditions optimised for the transport of copper are inadequate for lead and mercury. In fact, the inefficacy of their transport could be due, as regards lead, to the slow diffusion of the complex through the membrane, while mercury remained in the organic phase because of the high stability of the mercury‐carrier complex. Selectivity tests using binary mixtures of the metal ions showed TE14DT’s capability to transport copper or cadmium also in the presence of lead in the source phase. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)