Synthesis, Characterization, and Reaction of Crystalline Fischer’s Glucopyranosyl Isocyanate | Zendy

Ichikawa Yoshiyasu | Zendy; Matsukawa Yohei | Zendy; Nishiyama Taihei | Zendy; Isobe Minoru | Zendy

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Synthesis, Characterization, and Reaction of Crystalline Fischer’s Glucopyranosyl Isocyanate

Author(s) -

Ichikawa Yoshiyasu,

Matsukawa Yohei,

Nishiyama Taihei,

Isobe Minoru

Publication year - 2004

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200300617

Subject(s) - chemistry , isocyanate , anomer , organic chemistry , characterization (materials science) , stereochemistry , polymer chemistry , nanotechnology , polyurethane , materials science

We have established a simple method for the preparation of crystalline Fischer’s glucopyranosyl isocyanate 1 . NMR spectroscopic analysis of 1 allowed the unambiguous determination of the stereochemistry at the anomeric position. Synthetic applications of glucopyranosyl isocyanate 1 were examined by its reactions with amines and alcohols to furnish a wide variety of neoglycoconjugates. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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