Cycloaddition Reactions of 1,4‐Dihydronaphthalene‐1,4‐epoxide with Cyclohexadiene and 7‐(Methoxycarbonyl)cycloheptatriene: Selectivity in Additions | Zendy

Menzek Abdullah | Zendy; Altundaş Aliye | Zendy; Çoruh Ufuk | Zendy; Akbulut Nihat | Zendy; López Ezequiel M. Vázquez | Zendy; Hökelek Tuncer | Zendy; Erdönmez Ahmet | Zendy

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Cycloaddition Reactions of 1,4‐Dihydronaphthalene‐1,4‐epoxide with Cyclohexadiene and 7‐(Methoxycarbonyl)cycloheptatriene: Selectivity in Additions

Author(s) -

Menzek Abdullah,

Altundaş Aliye,

Çoruh Ufuk,

Akbulut Nihat,

López Ezequiel M. Vázquez,

Hökelek Tuncer,

Erdönmez Ahmet

Publication year - 2004

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200300569

Subject(s) - cycloaddition , cycloheptatriene , chemistry , selectivity , epoxide , naphthalene , medicinal chemistry , adduct , halogenation , organic chemistry , catalysis

Cycloaddition reactions of naphthalene‐1,4‐epoxide ( 1 ) with both 7‐(methoxycarbonyl)cycloheptatriene ( 2 ) and cyclohexadiene ( 4 ) give adducts of type 3 and 5 exclusively. Selectivity was observed for the cycloaddition and bromination reactions, but neighboring group participation also occurrs in the latter. The formation of the products is discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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