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One‐Pot Synthesis of α‐Amino Phosphonates Using Samarium Diiodide as a Catalyst Precursor
Author(s) -
Xu Fan,
Luo Yiqin,
Deng Mingyu,
Shen Qi
Publication year - 2003
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200300545
Subject(s) - chemistry , samarium diiodide , catalysis , samarium , organic chemistry , reaction conditions , phosphonate , combinatorial chemistry
A simple and efficient preparation of α‐amino phosphonates under relatively mild conditions by the one‐pot reaction of aldehydes with amines and dialkyl phosphites using catalytic amounts of SmI 2 is described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)