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Efficient Synthesis of Doubly Connected Primary Face‐to‐Face Cyclodextrin Homo‐Dimers
Author(s) -
Lecourt Thomas,
Mallet JeanMaurice,
Sinaÿ Pierre
Publication year - 2003
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200300267
Subject(s) - chemistry , metathesis , ring closing metathesis , yield (engineering) , alkyl , cyclodextrin , stereochemistry , primary (astronomy) , salt metathesis reaction , medicinal chemistry , organic chemistry , polymerization , astronomy , metallurgy , polymer , materials science , physics
“Head‐to‐head” type α‐ and β‐cyclodextrin homo‐dimers in which the two primary rims are doubly ligated through alkyl chains have been synthesised in high yield by acyclic diene metathesis (ADM), followed by ring‐closing metathesis (RCM). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)