Briarane, Erythrane, and Aquariane Diterpenoids from the Caribbean Gorgonian  Erythropodium caribaeorum | Zendy

TaglialatelaScafati Orazio | Zendy; Craig Kyle S. | Zendy; Rebérioux Delphine | Zendy; Roberge Michel | Zendy; Andersen Raymond J. | Zendy

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Briarane, Erythrane, and Aquariane Diterpenoids from the Caribbean Gorgonian Erythropodium caribaeorum

Author(s) -

TaglialatelaScafati Orazio,

Craig Kyle S.,

Rebérioux Delphine,

Roberge Michel,

Andersen Raymond J.

Publication year - 2003

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200300214

Subject(s) - gorgonian , chemistry , terpene , stereochemistry , diterpene , ecology , biology , coral

Seven new diterpenoids belonging to the briarane [erythrolides R ( 5 ), S ( 6 ), T ( 7 ), and U ( 8 )], erythrane [erythrolide V ( 9 )], and aquariane [aquariolides B ( 10 ) and C ( 11 )] skeletal classes have been isolated from the encrusting gorgonian Erythropodium caribaeorum . The structures of the new compounds were elucidated by spectroscopic analysis and chemical interconversions. A biogenetic proposal that links carbon skeletons found in E. caribaeorum diterpenoids is presented. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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