A New N,P‐Ligand with Achiral  gem ‐Dimethyloxazoline for Palladium( II )‐Catalyzed Cyclization of 1,6‐Enynes: Transition State Probe for the  N / C trans  Mode in Mizoroki−Heck‐Type C−C Bond Formation | Zendy

Hatano Manabu | Zendy; Yamanaka Masahiro | Zendy; Mikami Koichi | Zendy

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A New N,P‐Ligand with Achiral gem ‐Dimethyloxazoline for Palladium( II )‐Catalyzed Cyclization of 1,6‐Enynes: Transition State Probe for the N / C trans Mode in Mizoroki−Heck‐Type C−C Bond Formation

Author(s) -

Hatano Manabu,

Yamanaka Masahiro,

Mikami Koichi

Publication year - 2003

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200300196

Subject(s) - chemistry , palladium , ligand (biochemistry) , catalysis , enantioselective synthesis , stereochemistry , medicinal chemistry , transition metal , organic chemistry , receptor , biochemistry

A highly effective C 1 ‐symmetric gem ‐dimethyl N,P‐ligand has been developed for enantioselective palladium( II )‐catalyzed carbocyclization of 1,6‐enynes, in which the N / C trans mode is established for the first time in the “Mizoroki−Heck‐type” transition state by virtue of the C 1 ‐symmetric N,P‐ligand. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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