Preparation and Characterization of Sulfonyl‐Azafulleroid and Sulfonylaziridino‐Fullerene Derivatives | Zendy

Ulmer Lars | Zendy; Mattay Jochen | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Preparation and Characterization of Sulfonyl‐Azafulleroid and Sulfonylaziridino‐Fullerene Derivatives

Author(s) -

Ulmer Lars,

Mattay Jochen

Publication year - 2003

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200300122

Subject(s) - sulfonyl , chemistry , fullerene , substituent , electrochemistry , thermal decomposition , medicinal chemistry , organic chemistry , alkyl , electrode

Thermolysis of several sulfonyl azides in the presence of C 60 leads either to aza[60]fulleroids or to mixtures of aza[60]fulleroids and corresponding aziridino‐fullerenes, depending on the substituent at the sulfonyl group. In all cases, 1,2‐closed aziridino‐fullerenes can be obtained from azafulleroids by irradiation. Addition of sulfonyl azides to C 70 only yields azafulleroids with C s ‐symmetry. Cyclic‐voltammetric measurements revealed that there is no significant change of electrochemical properties compared to C 60 and C 70 . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research