Stereoselective Synthesis of (−)‐Deacetylanisomycin | Zendy

Merino Pedro | Zendy; Franco Santiago | Zendy; Lafuente Diego | Zendy; Merchan Francisco | Zendy; Revuelta Julia | Zendy; Tejero Tomas | Zendy

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Stereoselective Synthesis of (−)‐Deacetylanisomycin

Author(s) -

Merino Pedro,

Franco Santiago,

Lafuente Diego,

Merchan Francisco,

Revuelta Julia,

Tejero Tomas

Publication year - 2003

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200300091

Subject(s) - chemistry , stereoselectivity , nitrone , selectivity , yield (engineering) , derivative (finance) , nucleophilic addition , nucleophile , stereochemistry , grignard reaction , combinatorial chemistry , organic chemistry , reagent , catalysis , cycloaddition , materials science , financial economics , economics , metallurgy

A stereoselective synthesis of (−)‐deacetylanisomycin has been achieved from a nitrone derived from L ‐threose in 6 steps and 53.7% overall yield. The key step of the synthesis is the nucleophilic addition of a Grignard derivative with complete diastereofacial selectivity. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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