The Aldol‐Grob Reaction: Regioselective Synthesis of ( E )‐Alkenes from Aldehydes and Ketones with Ytterbium Triflate Catalysis | Zendy

Curini Massimo | Zendy; Epifano Francesco | Zendy; Maltese Federica | Zendy; Marcotullio Maria Carla | Zendy

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The Aldol‐Grob Reaction: Regioselective Synthesis of ( E )‐Alkenes from Aldehydes and Ketones with Ytterbium Triflate Catalysis

Author(s) -

Curini Massimo,

Epifano Francesco,

Maltese Federica,

Marcotullio Maria Carla

Publication year - 2003

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200300076

Subject(s) - chemistry , aldol reaction , trifluoromethanesulfonate , regioselectivity , catalysis , organic chemistry , hydrate , ketone , ytterbium , aldol condensation , aldehyde , solvent , medicinal chemistry , physics , optoelectronics , doping

A simple, good yielding and solvent‐free aldol‐Grob reaction sequence, catalysed by Yb(OTf) 3 hydrate, affording ( E )‐alkenes regioselectively from aldehydes and ketones is described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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