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Flash Vacuum Thermolysis of 1‐Azabicyclo[1.1.0]butanes. Photoelectron Spectrum of 3‐Phenyl‐2‐azabuta‐1,3‐diene
Author(s) -
Bartnik Romuald,
Baylère Patrick,
Chrostowska Anna,
Galindo Alberto,
Leśniak Stanislaw,
PfisterGuillouzo Geneviève
Publication year - 2003
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200300060
Subject(s) - chemistry , thermal decomposition , flash (photography) , diene , x ray photoelectron spectroscopy , flash vacuum pyrolysis , decomposition , medicinal chemistry , photochemistry , organic chemistry , pyrolysis , chemical engineering , art , natural rubber , engineering , visual arts
The reaction behaviour of 1‐azabicyclo[1.1.0]butanes under flash vacuum thermolysis (FVT) conditions was studied. It has been found that the thermal rearrangement of title compounds produces unstable 2‐aza‐1,3‐dienes. The formation of these products was established by reduction, by Diels−Alder reactions and by UV photoelectron spectroscopy. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)