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Very Rapid Preparation of SmI 2 by Sonic Treatment of Iodoform and Metallic Samarium
Author(s) -
Concellón José M.,
RodríguezSolla Humberto,
Bardales Eva,
Huerta Mónica
Publication year - 2003
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200210669
Subject(s) - iodoform , samarium , diiodomethane , chemistry , sonication , iodine , metal , nuclear chemistry , heptanal , inorganic chemistry , organic chemistry , chromatography , catalysis , aldehyde , surface energy
Abstract A very rapid preparation of SmI 2 by sonication of a mixture of metallic samarium and iodoform in THF is described. To prove the synthetic applications of the obtained SmI 2 several high‐yielding reactions were carried out. Preliminary results for the generation of SmI 2 in THF by sonication from diiodomethane, 1,2‐diiodoethane, or iodine are also described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)