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The Synthesis of Fused Ring Systems Utilising the Intramolecular Addition of Alkenyl Radicals to Furans
Author(s) -
Demircan Aydin,
Parsons Philip J.
Publication year - 2003
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200210329
Subject(s) - chemistry , intramolecular force , radical , cyclopentene , ring (chemistry) , stereochemistry , furan , medicinal chemistry , organic chemistry , catalysis
Studies on the intramolecular addition of alkenyl radicals to furans are reported. The alkenyl radicals undergo a 5‐exo‐trig addition to furans and the resulting spirocyclic intermediate can fragment to give substituted cyclopentene rings. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)