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(Aryl)(phosphanyl)Carbene: Ground‐ and Excited‐State Reactions
Author(s) -
DespagnetAyoub Emmanuelle,
Gornitzka Heinz,
Bourissou Didier,
Bertrand Guy
Publication year - 2003
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200200657
Subject(s) - carbene , cyclopropanation , chemistry , aryl , trifluoromethyl , singlet state , ground state , excited state , medicinal chemistry , diazo , photochemistry , organic chemistry , catalysis , alkyl , physics , quantum mechanics , nuclear physics
Cyclopropanation, carbene coupling, and photolytically induced 1,2‐migration reactions are reported for the stable singlet [bis(diisopropylamino)phosphanyl][ o , o ′‐bis(trifluoromethyl)phenyl]carbene ( 1 ). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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