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Characterization of Trimethylolpropane‐Based Biolubricant
Author(s) -
Nie Jieyu,
Shim Youn Young,
Shen Jianheng,
Tse Timothy J.,
Reaney Martin J. T.
Publication year - 2020
Publication title -
european journal of lipid science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.614
H-Index - 94
eISSN - 1438-9312
pISSN - 1438-7697
DOI - 10.1002/ejlt.202000025
Subject(s) - chemistry , trimethylolpropane , brassica rapa , vegetable oil , avena , linum , organic chemistry , food science , botany , biochemistry , biology , polyurethane , gene
The oxidative stability index (OSI) of fatty acid methyl esters (FAME) and trimethylolpropane (TMP) esters or TMPE produced from five vegetable oils ( Brassica rapa L ., Linum usitatissimum L ., Zea mays L ., Brassica napus L ., Camelina sativa L.) are compared. The highest stability is observed in vegetable oils while the processed products are less stable. The major causes in loss of OSI are attributed to excess FAME in the crude product and the loss of natural antioxidants due to refinement with silica and celite. The low‐temperature flow properties of TMPE produced from four different vegetable oils ( B. juncea L., L. usitatissimum L., B. rapa L., and C. sativa L.) are investigated by proton nuclear magnetic resonance ( 1 H‐NMR). The T2 relaxations of different TMPE are measured to observe how the mobility of oil changed as temperature decreased. Increased oil mobility (represented by T2) is correlated with rising temperature. The Gaussian widths of the singlet in 1 H‐NMR spectra of each oil demonstrated increased molecular mobility as temperature increased. Extrapolation of the relation of T2 signals of these four oils indicates that T2 approached zero between 232 K and 239 K, suggesting the molecular motion leading to a T2 relaxation has largely ceased. Practical Applications : The OSI is determined for four vegetable oils as well as the product FAME and TMPE. The vegetable oils are more stable than their products. The loss of natural antioxidants during purification of FAME and TMPE contributes to the lower OSI compared to vegetable oil. The low‐temperature flow behavior of TMP‐based biolubricants is determined between 238 K and 298 K using T2 relaxation. As temperature decreases, a singlet resonance in 1 H‐NMR spectra attributed to TMP protons broadens until it disappears. The results suggest that the log of the spin‐spin relaxation time is linearly correlated with rising temperature and oil mobility.