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Cover Picture: Eur. J. Lipid Sci. Technol. 1∕2016
Publication year - 2016
Publication title -
european journal of lipid science and technology
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.614
H-Index - 94
eISSN - 1438-9312
pISSN - 1438-7697
DOI - 10.1002/ejlt.201670011
Subject(s) - homogeneous , chemistry , catalysis , kinetic energy , glycerol , nanoparticle , chemical engineering , computer science , nanotechnology , materials science , physics , organic chemistry , thermodynamics , engineering , quantum mechanics
Kinetic modeling of the quasi‐homogeneous oxidation of glycerol over unsupported gold particles in the liquid phase José Antonio Díaz, Elżbieta Skrzyńska, Jean‐Sébastien Girardon, Jamal Ftouni, Mickaël Capron, Franck Dumeignil and Pascal Fongarland DOI: 10.1002/ejlt.201500189 A robust kinetic model for the homogeneous catalytic glycerol (GLY) partial oxidation over Au nanoparticles is proposed, considering the base‐assisted non‐catalytic reaction and the eff ect of the reaction temperature, the NaOH/GLY & the GLY/Au ratios. Such a model enables better understanding of the mechanisms leading to oxidation and C‐C cleavage, which selectively occur over the Au nanoparticles. The obtained parameters can subsequently be used to design a reactor for scaling an industrial unit.