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Various radical polymerizations of glycerol‐based monomers
Author(s) -
Pham Phuoc Dien,
Monge Sophie,
Lapinte Vincent,
Raoul Yann,
Robin Jean Jacques
Publication year - 2013
Publication title -
european journal of lipid science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.614
H-Index - 94
eISSN - 1438-9312
pISSN - 1438-7697
DOI - 10.1002/ejlt.201200202
Subject(s) - monomer , acrylate , photopolymer , polymer chemistry , polymerization , methacrylate , copolymer , radical polymerization , glycerol , chemistry , allylic rearrangement , polymer , organic chemistry , catalysis
This paper aims at making the state of the art of the radical polymerizations of glycerol‐based monomers, especially (meth)acrylate and vinylic/allylic derivatives. Acrylate and methacrylate derivatives bearing numerous secondary groups like ester, cyclocarbonate, acetal, and urethane were involved in free radical polymerization and radical controlled polymerizations as well as in the photopolymerization. Glycerol‐based monomers bearing a vinylic or an allylic polymerizable group polymerize by acceptor–donor process and produce alternating copolymers. From all these monomers, the synthesis of functionalized polymers was possible, leading to various valuable applications.