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One step hydroxybromination of fatty acid derivatives
Author(s) -
Eren Tarık,
Küsefoğlu Selim H.
Publication year - 2004
Publication title -
european journal of lipid science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.614
H-Index - 94
eISSN - 1438-9312
pISSN - 1438-7697
DOI - 10.1002/ejlt.200300869
Subject(s) - oleic acid , chemistry , sunflower oil , yield (engineering) , organic chemistry , fatty acid , acetone , kenaf , infrared spectroscopy , mass spectrometry , chromatography , nuclear chemistry , food science , materials science , biochemistry , metallurgy , fiber
Hydroxybromination of methyl oleate, oleic acid and new sunflower oil (high oleic), in an acetone/water mixture by a one step reaction using N‐bromosuccinimide, was studied. The yield of bromohydrin products from oleic acid, methyl oleate and sunflower oil were 90%, 78% and 40%, respectively. Reaction products were analyzed by 1 H and 13 C nuclear magnetic resonance spectroscopy, infrared spectroscopy, gas chromatography, and mass spectrometry. The hydrobromide derivative of new sunflower oil was acrylated and polymerized to a new polymer.