Premium
Front Cover: Supramolecular Assemblies and Reversible De‐/ Rehydration in One‐Dimensional Dimethyltin Carboxylates (Eur. J. Inorg. Chem. 13/2022)
Author(s) -
Shankar Ravi,
Dubey Archishmati,
Jakhar Ekta,
Chauhan Priyanka,
KociokKöhn Gabriele
Publication year - 2022
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202200210
Subject(s) - chemistry , supramolecular chemistry , front cover , hydrate , ligand (biochemistry) , crystallography , bipyridine , crystal engineering , cover (algebra) , aqueous solution , stereochemistry , polymer chemistry , crystal structure , organic chemistry , receptor , engineering , mechanical engineering , biochemistry
The Front Cover shows the synthesis of one‐dimensional ladder‐like structures of dimethyltin carboxylates in an aqueous medium and highlights the role of chelating 2,2'‐bipyridine to control the dimensionality in the presence of 1,2,4,5‐benzenetetracarboxylate ligand. The structures reveal supramolecular assemblies formed by the inclusion of infinite water tapes [T4(0)A1] or the organic hydrate (bipy⋅6H 2 O). The study is a manifestation of reversible single crystal to single crystal structural transformation from P 2 1 / c to P 2 1 2 1 2 1 upon dehydration with conformational changes in the macrocycles. More information can be found in the Research Article by R. Shankar and co‐workers.