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Cover Feature: Fluorosulfonylferrocene, (Trifluoromethylsulfonyl)ferrocene and New Ferrocenyl Sulfonates: Directed ortho Lithiation and New Anionic Thia‐Fries Rearrangements at Ferrocene (Eur. J. Inorg. Chem. 47/2021)
Author(s) -
Boston Geanne M. R.,
Philipp Hendrik M.,
Butenschön Holger
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202101001
Subject(s) - ferrocene , chemistry , nucleophile , amide , reactivity (psychology) , lithium (medication) , medicinal chemistry , cover (algebra) , lithium amide , combinatorial chemistry , polymer chemistry , organic chemistry , catalysis , electrochemistry , medicine , mechanical engineering , alternative medicine , electrode , pathology , enantioselective synthesis , engineering , endocrinology
The Cover Feature shows the reactions of ferrocene fluorosulfonate vs . ferrocenyl fluorosulfone with non‐nucleophilic lithium amide bases leading to an anionic thia‐Fries rearrangement in the first case and to an ortho lithiation in the second case, highlighting the difference in reactivity of two similar ferrocene derivatives. More information can be found in the Full Paper by H. Butenschön and co‐workers.