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Dimethylsulfide Adducts of the Beryllium Halides
Author(s) -
Buchner Magnus R.,
ThomasHargreaves Lewis R.,
Kreuzer Lukas K.,
Spang Nils,
Ivlev Sergei I.
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202100812
Subject(s) - chemistry , halide , thioether , adduct , beryllium , nuclear magnetic resonance spectroscopy , spectroscopy , medicinal chemistry , organic chemistry , nuclear chemistry , quantum mechanics , physics
The thioether diadducts [(SMe 2 ) 2 BeCl 2 ], [(SMe 2 ) 2 BeBr 2 ] and [(SMe 2 ) 2 BeI 2 ] have been prepared and converted to the corresponding μ 2 ‐halido bridged monoadducts [(SMe 2 )BeCl 2 ] 2 , [(SMe 2 )BeBr 2 ] 2 and [(SMe 2 )BeI 2 ] 2 . These complexes have been characterized with IR and NMR spectroscopy as well as X‐ray crystallography. Furthermore, their long term stability in chlorinated solvents was tested, which yielded beryllate salts containing the [SMe 3 ] + cation.