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Front Cover: NMR‐Spectroscopic Detection of an Elusive Protonated and Coinage Metalated Silicide [NHC Dipp Cu(η 4 ‐Si 9 )H] 2− in Solution (Eur. J. Inorg. Chem. 36/2021)
Author(s) -
Streitferdt Verena,
Tiefenthaler Susanne M.,
Shenderovich Ilya G.,
Gärtner Stefanie,
Korber Nikolaus,
Gschwind Ruth M.
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202100733
Subject(s) - chemistry , protonation , nuclear magnetic resonance spectroscopy , silicide , front cover , transition metal , reagent , crystallography , inorganic chemistry , computational chemistry , stereochemistry , cover (algebra) , organic chemistry , silicon , ion , mechanical engineering , engineering , catalysis
The Front Cover shows a stylized representation of the compound [NHC Dipp Cu(η 4 ‐Si 9 )H] 2− in a cocktail of the reagents and the solvent liquid ammonia at low temperatures. This compound is the first simultaneously protonated and transition metal functionalized group 14 Zintl cluster characterized by X‐ray structure analysis and NMR spectroscopy. The employed methods extend like an umbrella from various of 1D‐ and 2D‐NMR experiments all the way to theoretical calculations. More information can be found in the Full Paper by N. Korber, R. M. Gschwind and co‐workers.