Premium
Heterogeneous Olefin Aziridination Reactions Catalyzed by Polymer‐Bound Tris(triazolyl)methane Copper Complexes
Author(s) -
Rodríguez Manuel R.,
Molina Francisco,
Etayo Pablo,
Pericàs Miquel A.,
Pérez Pedro J.,
DíazRequejo M. Mar
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202100526
Subject(s) - chemistry , catalysis , olefin fiber , copper , alkyl , tris , polystyrene , aryl , methane , polymer chemistry , organic chemistry , heterogeneous catalysis , polymer , filtration (mathematics) , combinatorial chemistry , biochemistry , statistics , mathematics
Efficient olefin aziridination has been achieved with a tris(triazolyl)methane copper catalyst supported onto polystyrene. Aryl, alkyl and methoxycarbonyl‐substituted olefins are converted into N ‐tosylaziridines in good to high yields. The solid catalyst is readily separated by filtration and recycled, allowing its reuse with no significant loss of the catalytic activity.