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Front Cover: Reactivity of Copper(I) Complexes Containing Ligands Derived from (1 S ,3 R )‐Camphoric Acid with Dioxygen (Eur. J. Inorg. Chem. 22/2021)
Author(s) -
Stöhr Fabian,
Kulhanek Niclas,
Becker Jonathan,
Göttlich Richard,
Schindler Siegfried
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202100395
Subject(s) - chemistry , front cover , copper , reactivity (psychology) , ligand (biochemistry) , diamine , cover (algebra) , polymer chemistry , kinetics , crystallization , crystallography , stereochemistry , organic chemistry , mechanical engineering , medicine , alternative medicine , pathology , engineering , biochemistry , receptor , physics , quantum mechanics
The Front Cover shows the reaction of dioxygen with a copper(I) complex containing a tetramethylated diamine ligand that is related to camphor. The formation of a short‐lived bis(μ‐oxido) copper complex was observed spectroscopically by low temperature stopped‐flow kinetics. Deuteration of the methyl groups enabled crystallization and structural characterization of this reactive intermediate. More information can be found in the Full Paper by R. Göttlich, S. Schindler and co‐workers.