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Reactivity Trends with Borylalkyl Copper(I) Species
Author(s) -
Corro Macarena,
Salvado Oriol,
González Sara,
DominguezMolano Paula,
Fernández Elena
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202100296
Subject(s) - chemistry , electrophile , reagent , reactivity (psychology) , copper , catalysis , combinatorial chemistry , the renaissance , organometallic chemistry , organoboron compounds , conquest , organic chemistry , medicine , art , ancient history , alternative medicine , pathology , history , art history
The renaissance on the application of gem ‐diborylalkanes from 2010, has allowed the conquest of new synthetic application towards C−C and C−N bond formation. The activation of gem ‐diborylalkanes by Cu(I) catalysts, generates active borylalky copper(I) species that are able to trap several electrophilic reagents, in an efficient way. In addition, the modification of Cu(I) complexes with chiral ligands, induces asymmetric platforms towards the synthesis of enantioenriched organoboron compounds.