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Front Cover: Heterobimetallic Carbene Complexes Bearing Cyclometalated Ir III /Rh III and Mixed NHC ∧ Py/PPh 3 Coordinated Pd II Centers: Structures and Tandem Catalysis (Eur. J. Inorg. Chem. 12/2021)
Author(s) -
Majumder Adhir,
Nath Saha Tarak,
Majumder Niladri,
Naskar Rajat,
Pal Kuntal,
Maity Ramananda
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202100135
Subject(s) - chemistry , front cover , tandem , carbene , catalysis , transfer hydrogenation , metal , medicinal chemistry , selectivity , combinatorial chemistry , stereochemistry , polymer chemistry , cover (algebra) , organic chemistry , ruthenium , mechanical engineering , materials science , engineering , composite material
The Front Cover shows the combined action of two different metal centers in heterobimetallic M III −Pd II (M=Rh, Ir) complexes, featuring cyclometalated M III and mixed NHC∧ Py/PPh 3 coordinated Pd II centers, during tandem Suzuki‐Miyaura/transfer hydrogenation reactions. The heterobimetallic complex, bearing cyclometalated Ir III and mixed NHC∧ PPh 3 donor ligands at the Pd II center, shows excellent selectivity for 4‐biphenylmethanol in the tandem reaction. More information can be found in the Full Paper by R. Maity and co‐workers.