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Cover Feature: A Sandwich‐Shaped Hexanuclear Silver Complex with a Giant Cavity Constructed from a Macrocycle with Inward Chelating Units (Eur. J. Inorg. Chem. 4/2021)
Author(s) -
Nakamura Takashi,
Feng Rui Yun,
Nabeshima Tatsuya
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202001169
Subject(s) - chemistry , denticity , chelation , cover (algebra) , ligand (biochemistry) , crystallography , molecule , polymer chemistry , stereochemistry , crystal structure , inorganic chemistry , organic chemistry , receptor , biochemistry , mechanical engineering , engineering
The Cover Feature shows a macrocyclic hexanuclear silver complex with a giant cavity. Six silver centers are sandwiched by two molecules of a macrocyclic ligand possessing six pap (2‐[(pyridin‐2‐ylmethylene)amino]phenol) chelating units, and the metals are arranged on the wall of the internal cavity. The pap unit binds to the silver as an NN bidentate ligand. The beautiful structure of the metallomacrocycle is represented as an elegant accessory. More information can be found in the Full Paper by T. Nabeshima and co‐workers.