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Front Cover: Synthesis, Characterization and Electrochemical Reductive Properties of Complexes [Fe 2 (CO) 4 (κ 2 ‐P Ph 2 N R 2 )( μ ‐dithiolato)] Related to the H‐Cluster of [FeFe]‐H 2 ases (Eur. J. Inorg. Chem. 3/2021)
Author(s) -
Hobballah Ahmad,
Lounissi Sondes,
Motei Rachid,
Elleouet Catherine,
Pétillon François Y.,
Schollhammer Philippe
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202001144
Subject(s) - chemistry , cluster (spacecraft) , steric effects , proton , electrochemistry , front cover , redox , cover (algebra) , electronic structure , photochemistry , stereochemistry , combinatorial chemistry , computational chemistry , inorganic chemistry , electrode , mechanical engineering , physics , quantum mechanics , computer science , engineering , programming language
The Front Cover shows the fate of protons at a diiron site inspired by the H‐cluster of [FeFe]‐H 2 ases. Different conformations favor the capture of protons and their transfer to the diiron core, thus generating a suitable proton channel. Finding the right combinations of ligands for the design of efficient diiron electrocatalysts for proton reduction is like a 3D combination puzzle involving concerted electronic and steric effects through the choice of ligands around the dinuclear site. More information can be found in the Full Paper by C. Elleouet, P. Schollhammer and co‐workers.