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Unveiling the Zirconium and Hafnium Speciation in Fluoride‐Nitric Acid Solutions by Paper Spray Ionization Mass Spectrometry Combined with DFT Calculations
Author(s) -
Bertoli Alexandre C.,
Miguita Ana Gabriella C.,
Mingote Raquel M.,
Augusti Rodinei,
Duarte Hélio A.
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202001140
Subject(s) - chemistry , hafnium , zirconium , fluoride , aqueous solution , nitric acid , chemical stability , dimer , inorganic chemistry , valence (chemistry) , mass spectrometry , organic chemistry , chromatography
Paper spray ionization mass spectrometry (PSI‐MS) was used to detect a variety of species of hafnium and zirconium present in an aqueous acid solution containing NO 3 − and F − anions. This solution mimetics the acid waters used in separation/extraction processes. Hence, the information provided by PSI‐MS is combined with the results achieved from DFT calculations to confirm the nature and stability of each species. In the adopted experimental conditions, Zr(IV) appears coordinated with F − , NO 3 − and H 2 O to generate mainly the dimer [Zr 2 F 3 OH(NO 3 ) 2 (H 2 O) 5 ] 2+ , among other complexes, with remarkable thermodynamic stability (−48.7 kcal mol −1 ). On the other hand, Hf(IV) emerges predominantly coordinated with NO 3 − and F − anions. The hafnium monomers [HfF 4 NO 3 ] − and [HfF 3 (NO 3 ) 2 ] − have thermodynamic stability related to the electron pairing of the valence layer. In the gas phase, the fluoroanions of Zr(IV) demonstrated a high electronic affinity and free energy via DFT (−156.7 kcal mol −1 ) correlating thermodynamic stability to the experimental (−47 kcal mol −1 ), for the formation reaction of [ZrF 5 ] − . Besides, the presence of fluoride and nitrate in the reaction mixture induces the formation of dimers connected in μ 2 ‐F bridges, with coordination 7 and 8 of the central atom. Finally, the results described herein are promising studies of chemical speciation of cationic metals in an aqueous environment, a challenging subject whose importance will grow in the coming years.