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Ultrafast Synthesis of Wavy Gold‐Silver Alloy Nanowires with Tunable Diameters in the Range of 2‐10 nm via a Seed‐Mediated Co‐Reduction
Author(s) -
Wu Quansen,
Zhang Gongguo,
Ma Yanyun,
Li Mengfan,
Liu Feng,
Huang Hongwen,
Liu Maochang,
Zheng Yiqun
Publication year - 2021
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202001137
Subject(s) - nanowire , chemistry , alloy , absorbance , chemical engineering , ultrashort pulse , yield (engineering) , nanotechnology , materials science , metallurgy , organic chemistry , optics , laser , physics , chromatography , engineering
We report an ultrafast synthesis of wavy gold‐silver (AuAg) nanowires with tunable diameters via a seed‐mediated co‐reduction. The success of current strategy relies on the use of an elevated reaction temperature to accelerate the synthesis to be completed within several minutes and the use of Au seeds with controlled sizes to enable the manipulation over their diameters in the range of 2–10 nm. The presence of chloride‐contained quaternary ammonium surfactant and excessive reductant have been demonstrated to be critical for the high‐yield formation of AuAg products with the unique morphology of wavy nanowire. Due to the advantage in size control, the size effect on the plasmonic behavior of AuAg alloy wavy nanowires is investigated, where the products with sub‐5 nm diameter exhibit a broad shoulder absorbance peak in their spectrum.