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Bis(6‐diphenylphosphino‐acenaphth‐5‐yl)sulfoxide: A New Ligand for Late Transition Metal Complexes
Author(s) -
Meyer Fabio,
Hupf Emanuel,
Lork Enno,
Grabowsky Simon,
Mebs Stefan,
Beckmann Jens
Publication year - 2020
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202000610
Subject(s) - chemistry , sulfoxide , transition metal , ligand (biochemistry) , metal , sulfur , crystallography , coordination complex , stereochemistry , medicinal chemistry , inorganic chemistry , catalysis , organic chemistry , biochemistry , receptor
The synthesis of the new ligand bis(6‐diphenylphosphinoacenaphth‐5‐yl)sulfoxide, [6‐(Ph 2 P)‐5‐Ace‐6] 2 ‐SO ( 1 ), is presented along with six transition metal complexes thereof, namely, 1· MCl (M = Rh, Cu, Ag, Au) and 1· MCl 2 (M = Ni, Pd). Within these novel complexes, close metal‐sulfur distances are observed and the nature of the M–S coordination, as well as the response of the + S–O – bond, are investigated in detail with a set of spectroscopic, crystallographic and real‐space bonding indicators.