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Simultaneous Measurement of the Emission Quantum Yield and Local Temperature: The Illustrative Example of SrF 2 :Yb 3+ /Er 3+ Single Crystals
Author(s) -
Brites Carlos D. S.,
Kuznetsov Sergey V.,
Konyushkin Vasilii A.,
Nakladov Andrey N.,
Fedorov Pavel P.,
Carlos Luís D.
Publication year - 2020
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.202000113
Subject(s) - quantum yield , photoluminescence , luminescence , yield (engineering) , chemistry , excitation , quantum , analytical chemistry (journal) , atomic physics , optoelectronics , thermodynamics , materials science , optics , fluorescence , physics , quantum mechanics , chromatography
The emission quantum yield is one of the key figures of merit to evaluate the photoluminescence performance of luminescent materials. The emission quantum yield of upconverting materials is still not widely reported due to technical difficulties and intricate dependence on the excitation power density that is mirrored in a temperature increase. This work describes the simultaneous determination of the emission quantum yield (for both downshifting and upconverting processes) and of the temperature by using the output of a commercial integrating sphere. The temperature is calculated by primary luminescence thermometry through the Boltzmann equation, analyzing the intensity ratio between the 2 H 11/2 , 4 S 3/2 → 4 I 15/2 transitions. The procedure is illustrated using of SrF 2 : Yb 3+ /Er 3+ single crystals with distinct Yb 3+ compositions and the effect of the Yb 3+ content on the emission quantum yield and the temperature increase of the sample.