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Tetrazine‐Based Metal‐Organic Frameworks as Scaffolds for Post‐Synthetic Modification by the Click Reaction
Author(s) -
Vinu Madhan,
Sivasankar Kulandaivel,
Prabu Samikannu,
Han JengLiang,
Lin ChiaHer,
Yang ChunChuen,
Demel Jan
Publication year - 2020
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201901230
Subject(s) - tetrazine , metal organic framework , chemistry , linker , click chemistry , crystallinity , combinatorial chemistry , surface modification , nanotechnology , organic chemistry , materials science , computer science , adsorption , crystallography , operating system
Metal‐organic frameworks are one of the most active research fields today. Despite the progress in recent years, synthesis of highly porous structures bearing functional groups for specific applications remains a challenge. Here, we describe synthesis of Zr(IV) and Hf(IV)‐based tetrazine containing metal‐organic frameworks, ZrTz‐68 and HfTz‐68 with pore size of 2.1 nm, specific surface area up to 4217 m 2 g –1 , and a UiO‐68 topology. The synthesis can be done on a multi‐gram scale from inexpensive linker 4,4'‐(1,2,4,5‐tetrazine‐3,6‐diyl)dibenzoic acid (H 2 TzDB). Moreover, because of the π‐conjugated tetrazine groups these MOFs can be easily post‐synthetically modified by a “click” reaction maintaining the crystallinity of the framework. Due to the diversity of “clickable” substituents, this strategy represents highly versatile tool for a wide range of applications.