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Dinuclear Copper Complexes Triply Bridged by a Tetraphosphane, rac ‐Ph 2 PCH 2 P(Ph)CH 2 P(Ph)CH 2 PPh 2
Author(s) -
Tanase Tomoaki,
Otaki Risa,
Okue Ayumi,
Nakamae Kanako,
Nakajima Takayuki
Publication year - 2019
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201901014
Subject(s) - chemistry , phosphorescence , copper , dichloromethane , luminescence , cover (algebra) , solid state , fluorescence , photochemistry , firefly protocol , polymer chemistry , crystallography , stereochemistry , organic chemistry , optoelectronics , optics , mechanical engineering , zoology , physics , solvent , biology , engineering
Invited for the cover of this issue is the group of Tomoaki Tanase at Nara Women's University, Japan. The cover image shows a dinuclear copper(I) complex triply bridged by rac ‐dpmppm with a series of diimino ligands as a “dicopper firefly” that switches its luminescence mechanisms to emit rapid fluorescence in dichloromethane solution and 3 MLCT phosphorescence in the solid state.