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Front Cover: Dinuclear Copper Complexes Triply Bridged by a Tetraphosphane, rac ‐Ph 2 PCH 2 P(Ph)CH 2 P(Ph)CH 2 PPh 2 (Eur. J. Inorg. Chem. 37/2019)
Author(s) -
Tanase Tomoaki,
Otaki Risa,
Okue Ayumi,
Nakamae Kanako,
Nakajima Takayuki
Publication year - 2019
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201901013
Subject(s) - chemistry , front cover , cover (algebra) , luminescence , copper , ligand (biochemistry) , phosphorescence , crystallography , solid state , photochemistry , fluorescence , stereochemistry , polymer chemistry , organic chemistry , receptor , optoelectronics , optics , mechanical engineering , engineering , physics , biochemistry
The Front Cover shows dinuclear copper(I) complexes triply bridged by a tetraphosphine rac ‐dpmppm ligand in Z‐form with a series of diimino ligands, which emit rapid fluorescence from loosely coordinated diimino ligands in CH 2 Cl 2 solution and 3 MLCT phosphorescence in the solid state. The “dicopper firefly” switches the luminescence mechanisms by fluxional flipping of the diimino ligands. More information can be found in the Full Paper by T. Tanase et al. For more on the story behind the cover research, see the Cover Profile.