Premium
Cover Feature: Variations in the Solid‐State Emissions of Clothespin‐Shaped Binuclear trans ‐Bis(salicylaldiminato)platinum(II) with Halogen Functionalities (Eur. J. Inorg. Chem. 31/2019)
Author(s) -
Ikeshita Masahiro,
Ito Mizuki,
Naota Takeshi
Publication year - 2019
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201900841
Subject(s) - chemistry , bimetallic strip , platinum , cover (algebra) , halogen , phosphorescence , solid state , crystallography , halogen bond , photochemistry , polymer chemistry , catalysis , organic chemistry , optics , mechanical engineering , alkyl , physics , engineering , fluorescence
The Cover Feature shows the contrasting emission properties of crystal polymorphs of a clothespin‐shaped bimetallic platinum(II) complex bearing iodine atoms. The polymorph with an interpenetrating alignment brought about by one‐dimensional infinite I⋯π interactions is less emissive, while the polymorph with a non‐interpenetrating alignment resulting from a two‐dimensional constraint network consisting of I⋯I and Pt⋯Pt interactions exhibits strong phosphorescence. More information can be found in the Full Paper by T. Naota et al.