A Sound Sequence to Triphenylphosphino Dibromoplatinum(II) Complexes – Solvothermal Preparation of  trans ‐[PtBr(µ‐Br)(PPh 3 )] 2 | Zendy

Fioco David | Zendy; Belli Dell'Amico Daniela | Zendy; Labella Luca | Zendy; Marchetti Fabio | Zendy; Samaritani Simona | Zendy

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A Sound Sequence to Triphenylphosphino Dibromoplatinum(II) Complexes – Solvothermal Preparation of trans ‐[PtBr(µ‐Br)(PPh 3 )] 2

Author(s) -

Fioco David,

Belli Dell'Amico Daniela,

Labella Luca,

Marchetti Fabio,

Samaritani Simona

Publication year - 2019

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201900711

Subject(s) - chemistry , bridge (graph theory) , pyridine , x ray crystallography , nuclear magnetic resonance spectroscopy , crystallography , sequence (biology) , molecule , diffraction , stereochemistry , organic chemistry , medicine , biochemistry , physics , optics

A sound synthetic procedure for the preparation of trans ‐[PtBr(µ‐Br)(PPh 3 )] 2 is described. The species was fully characterized and used to obtain [PtBr 2 (PPh 3 )(L)] complexes (L = DMSO, p ‐toluidine, pyridine) by a bridge‐splitting reaction. All products were fully characterized by NMR spectroscopy, together with cis ‐[PtBr 2 (PPh 3 )(NCCH 3 )], obtained as an intermediate in the synthesis of the dinuclear precursor. Cis ‐[PtBr 2 (PPh 3 )(NCCH 3 )] was also studied by X‐ray diffraction.

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