Polymeric Lead(II) Iodoacetate: Pb···I and I···I Non‐Covalent Interactions in the Solid State | Zendy

Adonin Sergey A. | Zendy; Novikov Alexander S. | Zendy; Sokolov Maxim N. | Zendy

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Polymeric Lead(II) Iodoacetate: Pb···I and I···I Non‐Covalent Interactions in the Solid State

Author(s) -

Adonin Sergey A.,

Novikov Alexander S.,

Sokolov Maxim N.

Publication year - 2019

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201900349

Subject(s) - chemistry , covalent bond , electrophile , metal , solid state , lone pair , crystallography , inorganic chemistry , atom (system on chip) , alkaline earth metal , alkali metal , crystal structure , non covalent interactions , organic chemistry , molecule , catalysis , hydrogen bond , computer science , embedded system

Two‐dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n ( 1 ) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1 , Pb is hepta‐coordinated; additionally, metal centers participate in non‐covalent I ··· I and Pb ··· I contacts. According to the analysis of XRD data and DFT calculations, the I ··· I non‐covalent interactions are crystal packing‐induced type I contacts, and Pb ··· I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.

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