Ammonia and Hydrazine from Coordinated Dinitrogen by Complexes of Iron(0) | Zendy

Field Leslie D. | Zendy; Li Hsiu L. | Zendy; Dalgarno Scott J. | Zendy; McIntosh Ruaraidh D. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Ammonia and Hydrazine from Coordinated Dinitrogen by Complexes of Iron(0)

Author(s) -

Field Leslie D.,

Li Hsiu L.,

Dalgarno Scott J.,

McIntosh Ruaraidh D.

Publication year - 2019

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201900058

Subject(s) - chemistry , triflic acid , hydrazine (antidepressant) , ammonia , medicinal chemistry , inorganic chemistry , potassium , nuclear magnetic resonance spectroscopy , catalysis , organic chemistry , chromatography

The iron(0) dinitrogen complexes [Fe(N 2 )(PP 3 R )] (PP 3 R = P(CH 2 CH 2 PR 2 ) 3 , R = Ph, i Pr, Cy) were synthesized by reduction of the precursor chloro complexes with potassium graphite. On reaction with triflic acid, [Fe(N 2 )(PP 3 R )] complexes afforded ammonia and hydrazine in yields of up to 23 and 16 % respectively. The complex [Fe(N 2 )(PP 3 Ph )] which has only been previously synthesized in situ, has now been isolated and fully characterized by 15 N NMR spectroscopy and by X‐ray crystallography.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research