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Cover Feature: The Self‐Assembly of Ag I ‐Containing Heterobimetallic Complexes with a Discriminatory N,P‐Based Heteroditopic Ligand (Eur. J. Inorg. Chem. 44/2018)
Author(s) -
Hutchinson Daniel John,
HeyHawkins Evamarie
Publication year - 2018
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201801387
Subject(s) - chemistry , cover (algebra) , ligand (biochemistry) , phosphole , crystallography , pyrimidine , ion , stereochemistry , feature (linguistics) , polymer chemistry , organic chemistry , receptor , biochemistry , philosophy , mechanical engineering , linguistics , engineering
The Cover Feature shows the unusual heterobimetallic dimeric complexes that are produced when our heteroditopic ligand is reacted with Ag I , Ag I /Zn II , or Ag I /Pb II ions. Trying to use self‐assembly to form heterobimetallic complexes with Ag I can sometimes be a gamble due to its promiscuous nature. However, the high discriminatory power of our ligand's pyrimidine‐hydrazone and phosphole based coordination pockets enables the reliable and efficient synthesis of these diverse complexes in one pot reactions. More information can be found in the Full Paper by D. J. Hutchinson and E. Hey‐Hawkins .