Dinuclear Cu I  and Ag I  Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties | Zendy

Titov Aleksei A. | Zendy; Filippov Oleg A. | Zendy; Smol'yakov Alexander F. | Zendy; Baranova Kristina F. | Zendy; Titova Ekaterina M. | Zendy; Averin Aleksey A. | Zendy; Shubina Elena S. | Zendy

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Dinuclear Cu I and Ag I Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties

Author(s) -

Titov Aleksei A.,

Filippov Oleg A.,

Smol'yakov Alexander F.,

Baranova Kristina F.,

Titova Ekaterina M.,

Averin Aleksey A.,

Shubina Elena S.

Publication year - 2019

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201801318

Subject(s) - chemistry , trifluoromethyl , copper , photoluminescence , reagent , metal , solid state , crystallography , photochemistry , medicinal chemistry , stereochemistry , organic chemistry , alkyl , physics , optics

New dinuclear silver(I) and copper(I) 3,5‐bis(trifluoromethyl)pyrazolate compounds were prepared by the reaction of the corresponding trinuclear metal complexes with tertiary phosphines (PPh 3 , PCy 3 ). In the case of copper(I) trinuclear pyrazolate it was shown that the product structure depends on the reagent ratio: mono‐ and dinuclear complexes were obtained. All the dinuclear complexes obtained exhibit light emission in the solid state under UV irradiation. The observed photoluminescence behavior was confirmed by the TD‐DFT study.

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