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Heterodinuclear Group 13 Element Complexes of N 4 O 6 ‐Type Dipyrrin with an Unsymmetrical Twisted Structure
Author(s) -
Saikawa Makoto,
Noda Takumu,
Matsuoka Ryota,
Nakamura Takashi,
Nabeshima Tatsuya
Publication year - 2019
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201801062
Subject(s) - chemistry , dimer , group (periodic table) , boron , main group element , structure type , crystallography , stereochemistry , crystal structure , transition metal , organic chemistry , catalysis
Heterodinuclear group 13 element complexes of an N 4 O 6 ‐type dipyrrin cyclic dimer were synthesized by the stepwise reaction with boron and group 13 elements (Al, Ga, and In). The macrocycles have a new type of unsymmetrical twisted (pseudo‐figure‐of‐eight) structure.