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Cover Feature: Rhodium(I) Complexes of N ‐Aryl‐Substituted Mono‐ and Bis(amidinates) Derived from Their Alkali Metal Salts (Eur. J. Inorg. Chem. 26/2018)
Author(s) -
Moos Eric M. B.,
GonzálezGallardo Sandra,
Radius Michael,
Breher Frank
Publication year - 2018
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201800736
Subject(s) - rhodium , chemistry , alkali metal , aryl , cover (algebra) , metal , chelation , catalysis , linker , polymer chemistry , combinatorial chemistry , lanthanide , organic chemistry , mechanical engineering , alkyl , engineering , ion , computer science , operating system
The Cover Feature shows a strategy to modify the metal‐metal distance in dinuclear rhodium(I) complexes based on linker‐bridged bis(amidinate) ligands. As part of the collaborative research center 3MET , our group aims at understanding the underlying principles governing cooperative effects in catalysis. To rationally synthesize polynuclear complexes with tuneable metal–metal distances, a series of chelating N‐donor ligands was developed, which would concomitantly have an influence on possible cooperative effects. More information can be found in the Full Paper by F. Breher et al.