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Preparation and Self‐Assembly of a 2:1 Polyoxometalate‐Fullerene C 60 Shape Amphiphile
Author(s) -
Zhou Shengju,
Wang Lin,
Yuan Zaiwu,
Chen Mengjun,
Zhang Geping,
Li Hongguang
Publication year - 2018
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201800717
Subject(s) - polyoxometalate , chemistry , fullerene , supramolecular chemistry , toluene , solvent , vesicle , amphiphile , self assembly , crystallography , buckminsterfullerene , organic chemistry , membrane , crystal structure , copolymer , polymer , biochemistry , catalysis
An organic‐inorganic hybrid ( 5 ) is synthesized where two Dawson polyoxometalate (POM) moieties are linked to one fullerene C 60 unit. In a POM‐friendly solvent such as DMSO, DMF and CH 3 CN, 5 forms small vesicles below 100 nm at a concentration of 37.3 mg mL –1 . When the concentration decreases to 9.0 mg mL –1 , detection of aggregates becomes difficult. However, supramolecular structures with diverse morphologies can be induced upon the addition of H 2 O or toluene. In DMSO/H 2 O and DMF/H 2 O systems, plates form, which break to debris and small vesicles at high volume percentage of H 2 O. In CH 3 CN/H 2 O mixtures, solid spheres form, which fail to further evolve into other self‐assembled structures. In DMSO‐based binary mixtures, the type of poor solvent has a big influence on the aggregation behavior of 5 , and replacing H 2 O with toluene transfers the aggregates from plates to multilamellar and multicellular vesicles. In contrast, in CH 3 CN‐based systems, the influence of the type of poor solvent is quite limited. Although the morphologies of the aggregates change a lot, their magnetic properties remain unchanged as confirmed by electron spin‐resonance measurements.