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Cover Feature: Heptanuclear Cage Cu II ‐Silsesquioxanes: Synthesis, Structure and Catalytic Activity (Eur. J. Inorg. Chem. 22/2018)
Author(s) -
Bilyachenko Alexey N.,
Levitsky Mikhail M.,
Korlyukov Alexander A.,
Khrustalev Victor N.,
Zubavichus Yan V.,
Shul'pina Lidia S.,
Shubina Elena S.,
Vologzhanina Anna V.,
Shul'pin Georgiy B.
Publication year - 2018
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201800558
Subject(s) - chemistry , crystallography , cover (algebra) , silsesquioxane , catalysis , homogeneous , copper , crystal structure , polymer chemistry , organic chemistry , physics , thermodynamics , mechanical engineering , engineering , polymer
The Cover Feature shows a previously unreported heptanuclear copper(II)‐silsesquioxane core that demonstrates fascinating catalytic properties in homogeneous oxidation. Two representatives of the family (RSiO 1.5 ) 14 (CuO) 7 , with R = Me and Ph, were synthesized by self‐assembly, and their molecular and crystal structures were established by single‐crystal X‐ray diffraction based on synchrotron radiation. More information can be found in the Full Paper by A. N. Bilyachenko, G. B. Shul'pin et al.